During electrolysis of sulphuric acid, which of the following proce...

During electrolysis of sulphuric acid, which of the following proce...

During electrolysis of sulphuric acid, which of the following processes is possible at anode? A. \( 2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \longrightarrow \mathrm{O}_{2}(\mathrm{~g})+4 \mathrm{H}^{+}(\mathrm{aq})+4 \mathrm{e}^{-} \underset{\mathrm{E}_{\text {cell }}}{\ominus}+1.23 \mathrm{~V} \) B. \( 2 \mathrm{SO}_{4}^{2-}(\mathrm{a} \mathrm{q}) \longrightarrow \mathrm{S}_{2} \mathrm{O}_{8}^{2-}(\mathrm{aq})+2 \mathrm{e}^{-} \quad \mathrm{E}_{\text {cell }}^{\ominus} 1.96 \mathrm{~V} \) Choose the correct option based on following statements. (i) Process \( \mathrm{A} \) is preferred at higher concentration of sulphuric acid. (ii) Process \( \mathrm{B} \) is preferred at higher concentration of sulphuric acid. (iii) Process A is preferred for dilute sulphuric acid. (iv) Process \( B \) is preferred for dilute sulphuric acid. (v) Both \( \mathrm{A} \) and \( \mathrm{B} \) are equally possible at higher concentration. (a) (v) and (iii) (b) (iii) and (ii) (c) (i) and (iv) (d) (v) and (iv) 📲PW App Link - https://bit.ly/YTAI_PWAP 🌐PW Website - https://www.pw.live